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Orthohydrogen

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Orthohydrogen

Molecular hydrogen occurs in two isomeric forms, one with its two proton spins aligned parallel (orthohydrogen), the other with its two proton spins aligned antiparallel (parahydrogen).[1] At room temperature and thermal equilibrium, hydrogen consists of approximately 75% orthohydrogen and 25% parahydrogen.

Nuclear spin states of H2

Each hydrogen molecule (H2) consists of two hydrogen atoms linked by a covalent bond. If we neglect the small proportion of deuterium and tritium which may be present, each hydrogen atom consists of one proton and one electron. Each proton has an associated magnetic moment, which is associated with the proton's spin of 1/2. In the H2 molecule, the spins of the two hydrogen nuclei (protons) couple to form a triplet state known as orthohydrogen, and a singlet state known as parahydrogen.

The triplet orthohydrogen state has total nuclear spin I = 1 so that the component along a defined axis can have the three values MI = 1, 0, or −1. The corresponding nuclear spin wavefunctions are |\uparrow \uparrow \rangle, 1/ \sqrt{2}(|\uparrow \downarrow \rangle +|\downarrow \uparrow \rangle) and |\downarrow \downarrow \rangle (in standard bra-ket notation). Each orthohydrogen energy level then has a (nuclear) spin degeneracy of three, meaning that it corresponds to three states of the same energy, although this degeneracy can be broken by a magnetic field.

The singlet parahydrogen state has nuclear spin quantum numbers I = 0 and MI = 0, with wavefunction 1/\sqrt{2}(|\uparrow \downarrow \rangle - |\downarrow \uparrow \rangle) . Since there is only one possibility, each parahydrogen level has a spin degeneracy of one and is said to be nondegenerate.

The ratio between the ortho and para forms is about 3:1 at standard temperature and pressure – a reflection of the ratio of spin degeneracies. However if thermal equilibrium between the two forms is established, the para form dominates at low temperatures (approx. 99.8% at 20 K[2]). Other molecules and functional groups containing two hydrogen atoms, such as water and methylene, also have ortho and para forms (e.g. orthowater and parawater), although their ratios differ from that of the dihydrogen molecule.

Thermal properties

Since protons have spin 1/2, they are fermions and the permutational antisymmetry of the total H2 wavefunction imposes restrictions on the possible rotational states the two forms of H2 can adopt. Orthohydrogen, with symmetric nuclear spin functions, can only have rotational wavefunctions that are antisymmetric with respect to permutation of the two protons. Conversely, parahydrogen with an antisymmetric nuclear spin function, can only have rotational wavefunctions that are symmetric with respect to permutation of the two protons. Applying the rigid rotor approximation, the energies and degeneracies of the rotational states are given by[3]

\begin{align}

 & E_{J}=\frac{J(J+1)\hbar ^{2}}{2I};\text{ }g_{J}=2J+1 \\ 

\end{align}.

The rotational partition function is conventionally written as

Z_{\text{rot}}=\sum\limits_{J=0}^{\infty }{g_{J}e^{-{E_{J}}/{k_{B}T}\;}}.

However, as long as these two spin isomers are not in equilibrium, it is more useful to write separate partition functions for each,

Z_{\text{para}}=\sum\limits_{\text{even }J}{(2J+1)e^/{2Ik_{B}T}\;}}\text{  ; }Z_{\text{ortho}}=3\sum\limits_{\text{odd }J}{(2J+1)e^/{2Ik_{B}T}\;}}.

The factor of 3 in the partition function for orthohydrogen accounts for the spin degeneracy associated with the +1 spin state. When equilibrium between the spin isomers is possible, then a general partition function incorporating this degeneracy difference can be written as

\begin{align} & Z_{\text{equil}}=\sum\limits_{J=0}^{\infty }{(2-(-1)^{J})(2J+1)e^/{2Ik_{B}T}\;}} \\ \end{align}

The molar rotational energies and heat capacities are derived for any of these cases from

\begin{align} & U_{\text{rot}}=RT^{2}\left( \frac{\partial \ln Z_{\text{rot}}}{\partial T} \right)\text{ ; }C_{v,\text{ rot}}=\left( \frac{\partial U_{\text{rot}}}{\partial T} \right) \\ \end{align}

Because of the antisymmetry-imposed restriction on possible rotational states, orthohydrogen has residual rotational energy at low temperature wherein nearly all the molecules are in the J = 1 state (molecules in the symmetric spin-triplet state cannot fall into the lowest, symmetric rotational state) and possesses nuclear-spin entropy due to the triplet state's threefold degeneracy. The residual energy is significant because the rotational energy levels are relatively widely spaced in H2; the gap between the first two levels when expressed in temperature units is twice the characteristic rotational temperature for H2,

\frac{E_{J=1}-E_{J=0}}{k_{B}}=2\theta _{rot}=\frac{\hbar ^{2}}{k_{B}I}=174.98\text{ K}.

This is the T = 0 intercept seen in the molar energy of orthohydrogen. Since "normal" room-temperature hydrogen is a 3:1 ortho:para mixture, its molar residual rotational energy at low temperature is (3/4) x 2Rθrot = 1091 J/mol, which is somewhat larger than the activated carbon, platinized asbestos, rare earth metals, uranium compounds, chromic oxide, or some nickel compounds[4] to accelerate the conversion of the liquid hydrogen into parahydrogen, or supply additional refrigeration equipment to absorb the heat that the orthohydrogen fraction will release as it spontaneously converts into parahydrogen. If orthohydrogen is not removed from liquid hydrogen, the heat released during its decay can boil off as much as 50% of the original liquid.[5]

The first synthesis of pure parahydrogen was achieved by Paul Harteck and Karl Friedrich Bonhoeffer in 1929.

Modern isolation of pure parahydrogen has been achieved utilizing rapid in-vacuum deposition of millimeters thick solid parahydrogen (pH2) samples which are notable for their excellent optical qualities.[6]

Further research regarding parahydrogen thinfilm quantum state polarization matrices for computation seems a likely future prospect for these material sets.


Use in NMR

When an excess of parahydrogen is used during hydrogenation reactions (instead of the normal mixture of orthohydrogen to parahydrogen of 3:1), the resultant product exhibits hyperpolarized signals in proton NMR spectra. This effect is called PHIP ("Parahydrogen Induced Polarisation") or PASADENA ("Parahydrogen and Synthesis allow dramatically enhanced nuclear alignment" – named this way as the first recognition of the effect was done by Bowers and Weitekamp of Caltech in Pasadena[7]) and has been utilized to study the mechanism of hydrogenation reactions, e.g.[8] [9] [10]

References

Other literature

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