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Degradation Pathways of Pcb Upon Gamma Irradiation

By Lepine, François

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Book Id: WPLBN0000122147
Format Type: PDF eBook
File Size: 0.4 MB
Reproduction Date: 2005

Title: Degradation Pathways of Pcb Upon Gamma Irradiation  
Author: Lepine, François
Volume:
Language: English
Subject: Government publications, United Nations., United Nations. Office for Disarmament Affairs
Collections: Government Library Collection, Disarmament Documents
Historic
Publication Date:
Publisher: United Nations- Office for Disarmament Affairs (Unoda)

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Lepine, F. (n.d.). Degradation Pathways of Pcb Upon Gamma Irradiation. Retrieved from http://www.ebooklibrary.org/


Description
Government Reference Publication

Excerpt
Introduction: In a previous publication (I), the effects of gamma irradiation on Aroclor 1260 in solution were investigated. Considerable modlcations of the polychlorinated biphenyl (PCB) gas chromatographic profile were observed at irradiation doses similar to the maximum recommended by the Food and Aericultural Ormnkation of the United Nations (,F AO.) for fogd processin; Interestingly, dechlorination was the sole degradation pathway observed. Most of the congeners for which levels were enhanced upon inadiation were apparently produced through the loss of an ortho chlorine atom from their immediate precursor. This degradation pathway is similar to that observed for W irradiation of PCB, a process that generates similar reaction intermediates, namely, PCB radicals (2,3).

 

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