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Influences on the Fraction of Hydrophobic and Hydrophilic Black Carbon in the Atmosphere : Volume 11, Issue 1 (13/01/2011)

By McMeeking, G. R.

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Book Id: WPLBN0003996002
Format Type: PDF Article :
File Size: Pages 34
Reproduction Date: 2015

Title: Influences on the Fraction of Hydrophobic and Hydrophilic Black Carbon in the Atmosphere : Volume 11, Issue 1 (13/01/2011)  
Author: McMeeking, G. R.
Volume: Vol. 11, Issue 1
Language: English
Subject: Science, Atmospheric, Chemistry
Collections: Periodicals: Journal and Magazine Collection (Contemporary), Copernicus GmbH
Historic
Publication Date:
2011
Publisher: Copernicus Gmbh, Göttingen, Germany
Member Page: Copernicus Publications

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Good, N., Mcfiggans, G., Petters, M. D., Coe, H., & Mcmeeking, G. R. (2011). Influences on the Fraction of Hydrophobic and Hydrophilic Black Carbon in the Atmosphere : Volume 11, Issue 1 (13/01/2011). Retrieved from http://www.ebooklibrary.org/


Description
Description: Centre for Atmospheric Science, University of Manchester, Manchester, UK. Black carbon (BC) is a short term climate forcer that directly warms the atmosphere, slows convection, and hinders quantification of the effect of greenhouse gases on climate change. The atmospheric lifetime of BC particles with respect to nucleation scavenging in clouds is controlled by their ability to serve as cloud condensation nuclei (CCN). To serve as CCN under typical conditions hydrophobic BC particles must acquire hygroscopic coatings. However, the quantitative relationship between coatings and hygroscopic properties for ambient BC particles is not known nor is the time scale for hydrophobic-to-hydrophilic conversion. Here we introduce a method for measuring the hygroscopicity of externally and internally mixed BC particles by coupling a single particle soot photometer with a humidified tandem differential mobility analyzer. We test this technique using uncoated and coated laboratory generated model BC compounds and apply it to characterize the hygroscopicity distribution of ambient BC particles. From these data we derive that the observed number fraction of BC that is CCN active at 0.2% supersaturation is generally low in an urban area near sources and that it varies with the trajectory of the airmass. We anticipate that our method can be combined with measures of air parcel physical and photochemical age to provide the first quantitative estimates for characterizing hydrophobic-to-hydrophilic conversion rates in the atmosphere.

Summary
Influences on the fraction of hydrophobic and hydrophilic black carbon in the atmosphere

Excerpt
Alexander, D. T. L., Crozier, P. A., and Anderson, J. R.: Brown carbon spheres in East Asian outflow and their optical properties, Science, 321, 833–836, doi:10.1126/science.1155296, 2008.; Baumgardner, D., Kok, G., and Raga, G.: Warming of the Arctic lower stratosphere by light absorbing particles, Geophys. Res. Lett., 31, L06117, doi:10.1029/2003GL018883, 2004.; Cooke, W. F. and Wilson, J. J. N.: A global black carbon aerosol model, J. Geophys. Res., 101, 19395–19409, 1996.; Baumgardner, D., Kok, G. L., and Raga, G. B.: On the diurnal variability of particle properties related to light absorbing carbon in Mexico City, Atmos. Chem. Phys., 7, 2517–2526, doi:10.5194/acp-7-2517-2007, 2007.; Chung, S. H. and Seinfeld, J. H.: Global distribution and climate forcing of carbonaceous aerosols, J. Geophys. Res., 107, D4407, doi:10.1029/2001JD001397, 2002.; Cubison, M. J., Coe, H., and Gysel, M.: A modified hygroscopic tandem DMA and a data retrieval method based on optimal estimation, J. Aerosol Sci., 36, 846–865, 2005.; Draxler, R. R. and Rolph, G. D.: HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Website (http://ready.arl.noaa.gov/HYSPLIT.php). NOAA Air Resources Laboratory, Silver Spring, MD, 2010.; Dusek, U., Reischl, G. P., and Hitzenberger, R.: CCN activation of pure and coated carbon black particles, Environ. Sci. Technol., 40, 1223–1230, 2006.; Fletcher, N. H.: Size effects in heterogeneous nucleation, J. Chem. Phys., 29, 572–576, 1958.; Gao, R. S., Schwarz, J. P., Kelly, K. K., Fahey, D. W., Watts, L. A., Thompson, T. L., Spackman, J. R., Slowik, J. G., Cross, E. S., Han, J.-H., Davidovits, P., Onasch, T. B., and Worsnop, D. R.: A novel method for estimating light-scattering properties of soot aerosols using a modified single-particle soot photometer, Aerosol Sci. Technol., 41, 125–135, doi:10.1080/02786820601118398, 2007.; Good, N., Topping, D. O., Duplissy, J., Gysel, M., Meyer, N. K., Metzger, A., Turner, S. F., Baltensperger, U., Ristovski, Z., Weingartner, E., Coe, H., and McFiggans, G.: Widening the gap between measurement and modelling of secondary organic aerosol properties?, Atmos. Chem. Phys., 10, 2577–2593, doi:10.5194/acp-10-2577-2010, 2010.; Gysel, M., Nyeki, S., Weingartner, E., Baltensperger, U., Giebl, H., Hitzenberger, H., Petzold, A., and Wilson, C. W.: Properties of jet engine combustion particles during the PartEmis experiment: hygroscopicity at subsaturated conditions, Geophys. Res. Lett., 30, 1566, doi:10.1029/2003GL016896, 2003.; Gysel, M., McFiggans, G. B., and Coe, H.: Inversion of tandem differential mobility analyser (TDMA) measurements, J. Aerosol. Sci., 40, 134–151, 2009.; Henning, S., Wex, H., Wennrich, C., Hennig, T., Kiselev, A., Snider, J. R., Rose, D., Dusek, U., Frank, G. P., Pöschl, U., Kristensson, A., Bilde, M., Tillmann, R., Kiendler-Scharr, A., Mentel, Th. F., Walter, S., Schneider, J., and Stratmann, F.: Soluble mass, hygroscopic growth, and droplet activation of coated soot particles during LACIS Experiment in November (LExNo), J. Geophys. Res., 115, D11206, doi:10.1029/2009JD012626, 2010.; Henson, B. F.: An adsorption model of insoluble particle activation: Application to black carbon, J. Geophys. Res., 11

 

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